Lynn Fontanne and husband Alfred Lunt were the King and Queen of Broadway. Though Fontanne had appeared in two earlier films in the silent era, the stage was her true metier. Look up her credits on IBDb, and you'll find consistent work from 1910 - 1958; look up her credits on IMDb, and you'll see four films, two television guest appearances, and three teleplays, including The Magnificent Yankee, which earned her and Lunt Emmy wins. Much was made in 1931 of MGM being able to nab the couple to recreate their smash stage hit of 1924, The Guardsman, and even more so once the success carried over into cinema. Despite Thalberg's best efforts, however, Fontanne and Lunt were not to be swayed: back to the boards of New York they tread.
Helen Hayes was an accomplished stage actress - she would eventually come to be known as the First Lady of the American Stage - when she joined her writer husband in Los Angeles. Once again, MGM did the coaxing, landing Hayes for her screen debut in The Sin of Madelon Claudet...provided they hire her husband to do the adapting, of course. Hayes wasn't crazy about the role or the film, but it led to a long and illustrious screen career, one that she was able to balance alongside a healthy stage career. Her asthma pushed her to retire from theatre work in 1971 after the revival of Harvey, but she continued doing films and TV roles through 1985. She's an EGOT-er, including two Oscars and two Tonys.
And with that intro done, here's they work they were honored for:

